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This study concerns the design and implementation of a STEM literacy program for 11th to 13th-grade high achieving students, mainly females. The program, funded by the Italian Ministry of Equal Opportunities, aims at reducing the gender gap in the STEM disciplines and at orienting students towards university studies. We carried out a qualitative analysis of the students’ perception in terms of (1) a-priori expectations about the STEM literacy program and (2) a-posteriori thoughts and reflections about the attended course. Our analysis shows that students aspiring to participate had strong motivations with respect to the program; moreover, most students who participated in the program displayed satisfaction and an increase of awareness about their learning. We put a specific focus on the mathematical sessions of the curriculum, involving students as designers of educational resources. Some differences between male and female students arose for what concerns the perception of the program and the awareness of the impact of the STEM literacy program on their own learning.